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混凝土 16

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Effect of cavity defect on the triaxial mechanical properties of high-performance concrete

Yanbin ZHANG; Zhe WANG; Mingyu FENG

《结构与土木工程前沿（英文）》 2022年 第16卷 第5期   页码 600-614 doi: 10.1007/s11709-022-0821-5

摘要： The stress concentration of pipe structure or cavity defect has a great effect on the mechanical properties of the high-performance concrete (HPC) members in deep underground locations. However, the behaviour of HPC with cavities under triaxial compression is not understood, especially when pressurized liquid flows into the fractures from the cavity. This study aims to investigate the effect of the cavity and the confining pressure on the failure mechanisms, strengths, and deformation properties of HPC with a new experimental scheme. In this experiment, the pressurized liquid can only contact the surface of the sample in the cavity, while the other surfaces are isolated from the pressurized liquid. To further explore the effect of the cavity, the same experiments are also conducted on sealed and unsealed intact samples without a cavity. The failure modes and stress-strain curves of all types of the samples are presented. Under various confining pressures, all the samples with a cavity suffer shear failure, and there are always secondary tensile fractures initiating from the cavity sidewall. Additionally, it can be determined from the failure modes and the stress-strain curves that the shear fractures result from the sidewall failure. Based on the different effects of the cavity on the lateral deformations in different directions, the initiation of the sidewall fracture is well predicted. The experimental results show that both the increase of the confining pressure and the decrease of the cavity size are conducive to the initiation of sidewall fracture. Moreover, the cavity weakens the strength of the sample, and this study gives a modified Power-law criterion in which the cavity size is added as an impact factor to predict the strength of the sample.

关键词： high-performance concrete     cavity     conventional triaxial compression     pressurized liquid     modified power-law criterion    

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Fresh and hardened properties of high-performance fiber-reinforced concrete containing fly ash and rice

Nguyen-Trong HO; Viet Quoc DANG; Minh-Hieu NGUYEN; Chao-Lung HWANG; Trong-Phuoc HUYNH

《结构与土木工程前沿（英文）》 2022年 第16卷 第12期   页码 1621-1632 doi: 10.1007/s11709-022-0884-3

摘要： Although fibers are used only infrequently as an additive in concrete in the construction industry, fiber-enhanced concrete is known to provide a wide range of advantages over conventional concrete. The main objective of this study was to investigate the influences of fiber type and content on the mechanical properties and durability of high-performance fiber-reinforced concrete (HPFRC) designed using a novel densified mixture design algorithm with fly ash and rice husk ash. Three types of fiber, including polypropylene (PP) fiber, steel fiber (SF), and hybrid fiber (HF), were considered. Based on the results, the inclusion of fibers decreased HPFRC flowability, regardless of fiber type. Although the compressive strength of HPFRC with 1.6% PP fiber content was 11.2% below that of the reference HPFRC specimen at 91 d of curing age, the 91-d compressive strengths of both SF and HF-enhanced HPFRC specimens were significantly better than that of the reference HPFRC specimen. Furthermore, the HPFRC specimens incorporating SF and HF both exhibited better splitting tensile and flexural strengths as well as less drying shrinkage than the HPFRC specimens incorporating PP fiber. However, the fiber-enhanced specimens, especially those with added SF, registered less surface electrical resistivity and greater vulnerability to chloride ion penetration than the reference HPFRC specimen.

关键词： high-performance fiber-reinforced concrete     fly ash     rice husk ash     durability     mechanical strength    

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Recovery and reuse of floc sludge for high-performance capacitors

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1512-5

摘要：

• The feasibility of facile fabrication of capacitor from floc sludge is discussed.

关键词： Floc sludge     Porous carbon electrode     Energy storage performance     Supercapacitors    

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高性能多功能水泥基复合材料 Article

Victor C. Li

《工程（英文）》 2019年 第5卷 第2期   页码 250-260 doi: 10.1016/j.eng.2018.11.031

摘要：

混凝土是一种不断发展的材料，甚至高性能混凝土的定义也正随着时间的推移而发生变化。本文所说的混凝土材料的高性能特性是指那些直接影响我们生活质量的民用基础设施的理想耐久性、回弹性和可持续性的特性。这些特性包括拉伸延展性、自体裂缝宽度控制和材料的“绿色”环保性。此外，智能功能应旨在通过响应结构周围环境的变化来提高基础设施的耐久性、回弹性和可持续性以实现其理想功能，从而使材料的行为方式更类似于某些生物材料。本文基于工程水泥基复合材料（ECC）的最新研究进展，提出可以设计出具有高性能兼智能多功能性的混凝土材料，并且其具有满足 21 世纪民用基础设施预期需求的潜力。本文重点介绍了 ECC 的相关特性以及未来研究的方向。

关键词： 高性能混凝土     多功能     智能     水泥基复合材料     耐久性     回弹性     可持续性     基础设施    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Fabrication of high-performance pervaporation composite membrane for alkaline wastewater reclamation

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 709-719 doi: 10.1007/s11705-021-2078-2

摘要： Pervaporation desalination has a unique advantage to recycle concentrated salt solutions. The merit can be applied to treat alkaline wastewater if the membrane has superior alkali-resistance. In this paper, we used polyethylene microfiltration membrane as the substrate and deposited a glutaraldehyde crosslinked sodium carboxymethylcellulose layer by spray-coating. Pervaporation flux of the composite membrane reached 35€±€2 kg·m–2·h–1 with a sodium chloride rejection of 99.9%€±€0.1% when separating a 3.5 wt-% sodium chloride solution at 70 °C. The desalination performance was stable after soaking the membrane in a 20 wt-% NaOH solution at room temperature for 9 d and in a 10 wt-% NaOH solution at 60 °C for 80 h. Moreover, the membrane was stable in 4 wt-% sulfuric acid and a 500 mg·L−1 sodium hypochlorite solution. In a process of concentrating a NaOH solution from 5 to 10 wt-% at 60 °C, an average water flux of 23 kg·m–2·h–1 with a NaOH rejection over 99.98% was obtained.

关键词： pervaporation     alkaline solution concentration     polyethylene membrane     acid resistance     chlorine tolerance    

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Calculation of diagonal section and cross-section bending capacity for strengthening RC structure using high-performance

Shouping SHANG , Fangyuan ZHOU , Wei LIU ,

《结构与土木工程前沿（英文）》 2009年 第3卷 第3期   页码 330-338 doi: 10.1007/s11709-009-0046-x

摘要： Because there is a great demand of reinforcement and retrofitting of aged structures nationwide, as well as the rapid development of innovative building materials, the adoption of strengthening RC structures using new inorganic materials has become possible. High-performance ferrocement laminate (HPFL) is an effective method of strengthening concrete structure. High-performance ferrocement laminate is a new type of inorganic material with the advantages such as high strength, small contraction, good bonding properties, etc. This paper introduces the formula of cross-section bending capacity for strengthening concrete beams with HPEL. A comparative analysis of experimental data, as well as the calculation of diagonal section bearing capacity of concrete members, is given.

关键词： RC beams     high-performance ferrocement laminate (HPFL)     inorganic material     reinforcement    

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A pseudocapacitive molecule-induced strategy to construct flexible high-performance asymmetric supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1208-1220 doi: 10.1007/s11705-023-2304-1

摘要： The combination of high-voltage windows and bending stability remains a challenge for supercapacitors. Here, we present an “advantage-complementary strategy” using sodium lignosulfonate as a pseudocapacitive molecule to regulate the spatial stacking pattern of graphene oxide and the interfacial architectures of graphene oxide and polyaniline. Flexible and sustainable sodium lignosulfonate-based electrodes are successfully developed, showing perfect bending stability and high electronic conductivity and specific capacitance (521 F·g−1 at 0.5 A·g–1). Due to the resulting rational interfacial structure and stable ion-electron transport, the asymmetric supercapacitors provide a wide voltage window reaching 1.7 V, outstanding bending stability and high energy-power density of 83.87 Wh·kg–1 at 3.4 kW·kg–1. These properties are superior to other reported cases of asymmetric energy enrichment. The synergistic strategy of sodium lignosulfonate on graphene oxide and polyaniline is undoubtedly beneficial to advance the process for the construction of green flexible supercapacitors with remarkably wide voltage windows and excellent bending stability.

关键词： molecular synergy     pseudocapacitive lignosulfonate     flexible electronic devices     asymmetric supercapacitor     wide voltage windows    

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Cell surface protein engineering for high-performance whole-cell catalysts

Hajime Nakatani,Katsutoshi Hori

《化学科学与工程前沿（英文）》 2017年 第11卷 第1期   页码 46-57 doi: 10.1007/s11705-017-1609-3

摘要： Cell surface protein engineering facilitated by accumulation of information on genome and protein structure involves heterologous production and modification of cell surface proteins using genetic engineering, and is important for the development of high-performance whole-cell catalysts. In this field, cell surface display is a major technology by exposing target proteins, such as enzymes, on the cell surface using a carrier protein. The target proteins are fused to the carrier proteins that transport and tether them to the cell surface, as well as to a secretion signal. This paper reviews cell surface display systems for prokaryotic and eukaryotic cells from the perspective of carrier proteins, which determine the number of displayed molecules, and the localization, size, and direction ( or terminal anchoring) of the passengers. We also discuss advanced methods for displaying multiple enzymes and a new method for the immobilization of whole-cell catalysts using adhesive surface proteins.

关键词： cell surface engineering     surface display     whole-cell catalysts     bioprocess    

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Freshwater algae chemotaxonomy by high-performance liquid chromatographic (HPLC) analysis

Yansong HOU, Wei LIANG, Liping ZHANG, Shuiping CHENG, Feng HE, Zhenbin WU

《环境科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 84-91 doi: 10.1007/s11783-010-0283-1

摘要： The study of community composition of algae is essential for understanding the structure and dynamics of the aquatic ecosystem and for evaluating the eutrophic level of the water body. A high-performance liquid chromatographic (HPLC) method based on a reverse-phase C nonpolar column was developed for the main algal taxa, which includes cyanophytes, bacillariophytes, euglenophytes, dinophytes, and chlorophytes. Based on the elution order using HPLC, 19 pigments were identified, and they were chlorophyllide , 19′-butanoyloxyfucoxanthin, chlorophyll + , phephorbides , peridinin, methyl-chlorophyllide , fucoxanthin, neoxanthin, violaxanthin, myxoxanthophyll, diadinoxanthin, diatoxanthin, lutein, zeaxanthin, chlorophyll allomer, chlorophyll , chlorophyll allomer, chlorophyll , and β,β-carotene. A comparison study of cell microscopic counts and accessory pigment analysis indicated that HPLC analysis could be a useful tool for monitoring phytoplankton communities and their abundance.

关键词： high-performance liquid chromatographic (HPLC)     algae     pigment     chemotaxonomy    

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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

《化学科学与工程前沿（英文）》 2022年 第16卷 第10期   页码 1531-1531 doi: 10.1007/s11705-022-2241-4

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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 484-497 doi: 10.1007/s11705-021-2074-6

摘要： The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.

关键词： nickel phyllosilicate     flow-like structure     mechanical property     thermal stability     tribological performance    

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Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 226-235 doi: 10.1007/s11705-022-2198-3

摘要： Prussian blue and its analogs are extensively investigated as a cathode for ammonium-ion batteries. However, they often suffer from poor electronic conductivity. Here, we report a Ni2Fe(CN)6/multiwalled carbon nanotube composite electrode material, which is prepared using a simple coprecipitation approach. The obtained material consists of nanoparticles with sizes 30–50 nm and the multiwalled carbon nanotube embedded in it. The existence of multiwalled carbon nanotube ensures that the Ni2Fe(CN)6/multiwalled carbon nanotube composite shows excellent electrochemical performance, achieving a discharge capacity of 55.1 mAh·g–1 at 1 C and 43.2 mAh·g–1 even at 15 C. An increase in the ammonium-ion diffusion coefficient and ionic/electron conductivity based on kinetic investigations accounts for their high performance. Furthermore, detailed ex situ characterizations demonstrate that Ni2Fe(CN)6/multiwalled carbon nanotube composite offers three advantages: negligible lattice expansion during cycling, stable structure, and the reversible redox couple. Therefore, the Ni2Fe(CN)6/multiwalled carbon nanotube composite presents a long cycling life and high rate capacity. Finally, our study reports a desirable material for ammonium-ion batteries and provides a practical approach for improving the electrochemical performance of Prussian blue and its analogs.

关键词： nickel ferrocyanides     NH4+     electrochemistry     Prussian blue     aqueous ammonium ion batteries    

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Construction of NiCoO nanoflake arrays on cellulose-derived carbon nanofibers as a freestanding electrode for high-performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 691-703 doi: 10.1007/s11705-022-2268-6

摘要： Cellulose has a wide range of applications in many fields due to their naturally degradable and low-cost characteristics, but few studies can achieve cellulose-nanofibers by conventional electrospinning. Herein, we demonstrate that the freestanding cellulose-based carbon nanofibers are successfully obtained by a special design of electrospinning firstly, pre-oxidation and high-temperature carbonization (1600 °C), which display a superior electrical conductivity of 31.2 S·cm–1 and larger specific surface area of 35.61 m2·g–1 than that of the polyacrylonitrile-based carbon nanofibers (electrical conductivity of 18.5 S·cm–1, specific surface area of 12 m2·g–1). The NiCo2O4 nanoflake arrays are grown uniformly on the cellulose-based carbon nanofibers successfully by a facile one-step solvothermal and calcination method. The as-prepared cellulose-based carbon nanofibers/NiCo2O4 nanoflake arrays are directly used as electrodes to achieve a high specific capacitance of 1010 F·g–1 at 1 A·g–1 and a good cycling stability with 90.84% capacitance retention after 3000 times at 10 A·g–1. Furthermore, the all-solid-state symmetric supercapacitors assembled from the cellulose-based carbon nanofibers/NiCo2O4 deliver a high energy density of 62 W·h·kg–1 at a power density of 1200 W·kg–1. Six all-solid-state symmetric supercapacitors in series can also power a ‘DHU’ logo consisted of 36 light emitting diodes, confirming that the cellulose-based carbon nanofiber is a promising carbon matrix material for energy storage devices.

关键词： cellulose     carbon nanofibers     NiCo2O4     supercapacitors    

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HIGH-PERFORMANCE COMPUTATION AND ARTIFICIAL INTELLIGENCE IN PESTICIDE DISCOVERY: STATUS AND OUTLOOK

《农业科学与工程前沿（英文）》 2022年 第9卷 第1期   页码 150-154 doi: 10.15302/J-FASE-2021419

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标题 作者 时间 类型 操作

Effect of cavity defect on the triaxial mechanical properties of high-performance concrete

Yanbin ZHANG; Zhe WANG; Mingyu FENG

期刊论文

Fresh and hardened properties of high-performance fiber-reinforced concrete containing fly ash and rice

Nguyen-Trong HO; Viet Quoc DANG; Minh-Hieu NGUYEN; Chao-Lung HWANG; Trong-Phuoc HUYNH

期刊论文

Recovery and reuse of floc sludge for high-performance capacitors

期刊论文

高性能多功能水泥基复合材料

Victor C. Li

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Fabrication of high-performance pervaporation composite membrane for alkaline wastewater reclamation

期刊论文

Calculation of diagonal section and cross-section bending capacity for strengthening RC structure using high-performance

Shouping SHANG , Fangyuan ZHOU , Wei LIU ,

期刊论文

A pseudocapacitive molecule-induced strategy to construct flexible high-performance asymmetric supercapacitors

期刊论文

Cell surface protein engineering for high-performance whole-cell catalysts

Hajime Nakatani,Katsutoshi Hori

期刊论文

Freshwater algae chemotaxonomy by high-performance liquid chromatographic (HPLC) analysis

Yansong HOU, Wei LIANG, Liping ZHANG, Shuiping CHENG, Feng HE, Zhenbin WU

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

期刊论文

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

期刊论文

Construction of NiCoO nanoflake arrays on cellulose-derived carbon nanofibers as a freestanding electrode for high-performance

期刊论文

HIGH-PERFORMANCE COMPUTATION AND ARTIFICIAL INTELLIGENCE IN PESTICIDE DISCOVERY: STATUS AND OUTLOOK

期刊论文